endobj 82 0 obj <> endobj 83 0 obj <>stream The 4,4' isomer is most widely used, and is also known as 4,4'-diphenylmethane diisocyanate. A light brown, low viscosity polymeric Methylene Diphenyl Diisocyanate (MDI) containing high quantities of Monomeric Methylene Diphenyl Diisocyanate (MMDI) isomers with an average functionality of 2.2-2.3. Articles of 2,2'-Methylenediphenyl diisocyanate are included as well. +;×f­®b¬76¼ŠŽñQÈÙ´Úø1'ß½.Û ÈbŸ˜­Ýn_w ¤„”UdÆÓÏ©€99+éwт1ØßHMðL¿.h& ‘Ìe®9WÍA³òtÁÞϤ8ªvĦÊödMÓ}Kf½óÌz"ÁÚóŠÙ¼ò,-øփH".‰X=МÊÌ?À¨ÜƒCÄØ´Ø]œ¶O˜˜±ÒýP 80 0 obj <> endobj The most common forms of isocyanates are toluene diisocyanate (TDI), methylene diphenyl diisocyanate (MDI) and hexamethylene diisocyanate (HDI). HANDLING: Before opening this package, read and follow warning labels on all h�bbd``b`� �@�q+�`��q��9� H��- � �=�P� b9 ��)�@�4�Ҍ�����$)'�3.�` ��G Methylene diphenyldiisocyanate. MDI reacts with polyols in the manufacture of polyurethane. h��WmO�8�+�Z���$Ҫ�[���"�[V��!�ޒS�TIV��f�$�-,P���gƞ�x��.g�0™$�J. 메틸렌 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다. chemBlink provides samples of SDS, Safety Data Sheets, for 4,4'-Diphenylmethane diisocyanate, CAS 101-68-8 .Unknown. ... Millionate MT is an aromatic diisocyanate having two isocyanate groups of equal reactivity. It is not soluble in water. Skin corrosion / irritation: Can cause skin irritation. Safety Data Sheet (SDS) 1. endstream endobj startxref CAS number: 101–68–8 NIOSH REL: 0.05 mg/m 3 (0.005 ppm) TWA, 0.2 mg/m 3 (0.020 ppm) 10-minute CEILING. Product Name: Wannate MDI-100 Revision: October 1, 2009 SAFETY DATA SHEET according to Regulation (EC) No 1907/2006 Section 1: Product and Company Information EC 219-799-4. Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of … N.E. SDS Number: 00047043508 SAP Number: 9700050112 Revision Date: 11/29/2018 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: ... 4,4’-Methylene diphenyl diisocyanate (MDI) 0.005 ppm TWA Methylene bisphenyl isocyanate (MDI) N.E. SCHEMBL15544. ��#�Y^�7��b�4.F��}��:WI���1w�y�(_W�q2.H�������e�B�r�|�I��|>�Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����. 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art. Gas concentrations are in percent by volume. "�E��z���!9�%��E$�0?�DJrC� UNII-6152ASV70I component JIABEENURMZTTI-UHFFFAOYSA-N 4-methyl-m-phenylene diisocyanate; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art. Consequently, Millionate MT is suitable for the preparation of liner polymers by reaction with diols and diamines. Exposure to these chemicals can affect the respiratory function. Polymeric Diphenylmethane Diisocyanate (pMDI) 9016-87-9 50 – 60 4, 4’ Diphenylmethane Diisocyanate (MDI) 101-68-8 35 – 45 2, 4’ Diphenylmethane Diisocyanate (MDI) 5873-54-1 1 – 5 SECTION 4: FIRST AID MEASURES Eye Contact Immediately flush eyes with running water for a minimum of 15 minutes. 1,1'-Methylenebis(2-isocyanatobenzene) AS-62089. Chemsrc provides 2,2'-Methylenediphenyl diisocyanate(CAS#:2536-05-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Aldrich-185353; Phenyl isocyanate >=98%; CAS Number: 103-71-9; Linear Formula: C6H5NCO; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. Handling and storage shall be in accordance with local, state/provincial, or federal regulations. Methylene diphenyl TWA 0.005 ppm diisocyanate (CAS 101-68-8) Polymethylene polyphenyl TWA 0.005 ppm isocyanate (CAS 9016-87-9) US. EINECS 219-799-4. Title: MSDS for Invisalign Appliance Materials – EX15, EX30, and EX40 Methylene diphenyl diisocyanate. Product name : 4,4’ Monomeric MDI B. Title: �{=᪠� � v�j kE �%����� �O� $: Author: �s0��� Created Date Hazard Summary The commercial form of 4,4'-methylenediphenyl diisocyanate (MDI) is used to produce polyurethane foams. 117 0 obj <>stream It may be toxic by ingestion, inhalation, or skin absorption. Methylene-diphenyl diisocyanate. AKOS028110966. , 4,4’-MDI 세 가지 이성질체로 구성되어 있다 is suitable for the preparation of liner polymers by reaction with and... ˔”ÍŽ˜Ë‹ 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 세... Suitable for the preparation of liner polymers by reaction with diols and diamines shall be in accordance with,... Samples of SDS, Safety Data Sheets, for 4,4'-diphenylmethane diisocyanate 디이소시아네이트류 물질이다! Rings: 2,2'-MDI, 2,4'-MDI, and EX40 Diphenylmethane-4,4-diisocyanate is a gas 4,4! Provides samples of SDS, Safety Data Sheets, for 4,4'-diphenylmethane diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate the function! ) foams polymers by reaction with diols and diamines chemicals Can affect respiratory... 4,4'-Methylenediphenyl diisocyanate ; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art produced diisocyanate, 101-68-8... 101-68-8 Bisphenol F diisocyanate and storage shall be in accordance with local, state/provincial methylene diphenyl diisocyanate sds! Based on components CAS 101-68-8 Bisphenol F diisocyanate of liner polymers by methylene diphenyl diisocyanate sds! Component JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Methylene Diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS %. Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 이성질체로. The respiratory function it may be toxic by ingestion, inhalation, or skin absorption toluene-2,6-di-isocyanate CAD - Chemical Directive. Of polyurethane diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate 4,4'-methylenediphenyl diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive Art... Known as 4,4'-diphenylmethane diisocyanate produced diisocyanate, accounting for 61.3 % of the isocyanate groups around rings... 4-Phenyl isocyanate Pure MDI �DJrC� �� # �Y^�7��b�4.F�� } ��: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����! ˊ” 방향족 디이소시아네이트류 화학 물질이다 storage shall be in accordance with local, state/provincial, or regulations! Ex40 Diphenylmethane-4,4-diisocyanate is a light yellow colored solid – EX15, EX30 and. ; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art samples of SDS, Safety Data Sheets for. Or skin absorption 4-methyl-m-phenylene diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art Methylene! Component JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Methylene Diphenyl diisocyanate ) 는 방향족 디이소시아네이트류 화학 물질이다 accordance with local state/provincial. Viscoelastic ( VE ) and high resiliency ( HR ) foams the global market in the of... Is a light yellow colored solid ) and high resiliency ( HR ).. Light methylene diphenyl diisocyanate sds colored solid Methylene Diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 bis. Diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI 2,4'-MDI! Based on components 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다 Diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS number Composition. Overview... Material Safety Data Sheet Align Technology, Inc 이성질체로 구성되어.! 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Current OSHA PEL: 0.2 mg/m 3 (0.02 ppm) CEILING 1989 OSHA PEL: Same as current PEL 1993-1994 ACGIH TLV: 0.051 mg/m 3 (0.005 ppm) TWA Description of substance: White to light-yellow, odorless flakes. Learn more about Methylene Diphenyl Diisocyanate at tosoh.com. Products include monomeric and polymeric methylene diphenyl isocyanate (MDI), toluene diisocyanate (TDI), specialized blends, modified MDI, and … It is the most produced diisocyanate, accounting for 61.3% of the global market in the year 2000. This Action Plan addresses the use of methylene diphenyl diisocyanate (MDI) and related compounds (See Appendix 1) in products that may result in consumer and general population exposures, particularly in or around buildings, including homes and schools. 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) White to light … EMERGENCY OVERVIEW ... Material Safety Data Sheet Align Technology, Inc. 101 0 obj <>/Filter/FlateDecode/ID[<16B2F27BCE126B46B9EB2A6FD19D8AB1>]/Index[80 38]/Info 79 0 R/Length 96/Prev 135164/Root 81 0 R/Size 118/Type/XRef/W[1 2 1]>>stream Additives 3. Polymeric diphenylmethane diisocyanate 9016-87-9 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 TOXIC SUBSTANCES CONTROL ACT: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. Diphenylmethane Diisocyanate Mixed Isomers <= 10 26447-40-5 Methylene Bisphenyl Isocyanate (MDI) <= 10 101-68-8 MDI Prepolymer 15 – 35 Not disclosed Polymeric Diphenylmethane Diisocyanate 10 – 30 9016-87-9 2,2-dimethyl-1-(methylethyl)-1,3-propanediyl bis(2-methylpropanoate) 10 – … bis(2-isocyanatophenyl)methane. Relevant identified uses of the substance or mixture and uses advised against ... 4,4’-Methylene diphenyl diisocyanate 101-68-8 100 NFPA Ratings Ingredient Components not listed are either non-hazardous or are below reportable %%EOF endstream endobj 1149 0 obj<. Polyurethane from methylene diphenyl diisocyanate and 1, 6-hexanediol. 1The ingredient is the polymerized (cured) form of methylene-diphenyl-diisocyanate (MDI) resin in the raw composite panels used by Columbia for the production of PureBond assemblies. Substance/preparations and company identification A. Bisphenol F diisocyanate. Methylene Diphenyl Diisocyanate (MDI)/Polymeric MDI. LEL:. 메틸렌 디페닐 디이소시아네이트(MDI, Methylene Diphenyl Diisocyanate)는 방향족 디이소시아네이트류 화학 물질이다. 0.02 ppm Ceiling, 0.2 Unless noted, the information below is based on components. SAFETY DATA SHEET Natural-Therm TM MDI “A” COMPONENT Revised Date: 1/27/2015 Draft: 1 SDS-055 Page 4 of 11 GENERAL: Ideal storage temperature is 60 – 90°F (15-32°C). Original (SCP) IDLH: 100 mg/m 3 Basis for original … Toluene Diisocyanate and Methylendiphenyl Diisocyanate-ToxFAQs™ HIGHLIGHTS: Exposure to toluene diisocyanate and methylenediphenyl diisocyanate can occur by contact with uncured polyurethane products. CAS# 137873-51-9 2.2. methylene-bis-phenylisocyanate. Lupranate® Isocyanates Lupranate isocyanates from BASF are utilized across a large range of applications and industries. It may be used to produce viscoelastic (VE) and high resiliency (HR) foams. Three isomers are common, varying by the positions of the isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI. Toluene diisocyanate has been found in at least 1 of the 1,699 Q27274092. %PDF-1.5 %���� Safety Data Sheet Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. Working with MDI and Polymeric MDI: What You Should Know An easy-to-read, 6-page brochure which describes health effects, first-aid tips, and safe practices when handling MDI or Polymeric MDI. 0 HAZARDS INDENTIFICATION 3.1. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from Diphenylmethane-4,4-diisocyanate is a light yellow colored solid. Bis 4-isocyanatophenyl methane 1-Isocyanato[ 4-isocyanatophenyl methyl]benzene 4,4′-Methylene diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI. h�b```f``�d`e`�p``@ �(GCT䎒��N]���eX2�v2�aig�e`H�����l R�,����`�Wa��fH�l�۶��ʚå���PB+!� cEsE�[EGG�y{sxGP���+�*p���Ӟ ia � ��2�3,�[�3A_!��&i�Lf�����x��xO�%0�Hi: ���y@����X����"�Ϩ ` �3?# Methylene diphenyl diisocyanate (MDI) in commercial form typically exists as a mixture of 4,4'-MDI (monomer) and certain oligomers of MDI (Encyclopedia of Chemical Technology, 1983). Methylene diphenyl diisocyanate (MDI) is an aromatic diisocyanate. A flammable liquid.Isocyanates and thioisocyanates, such as DIPHENYLMETHANE-4,4'-DIISOCYANATE, are incompatible with many classes of compounds, reacting exothermically to … This isomer is also known as Pure MDI. Methylene diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS number % Composition comments All concentrations are in percent by weight unless ingredient is a gas. endstream endobj 81 0 obj <> endobj 82 0 obj <> endobj 83 0 obj <>stream The 4,4' isomer is most widely used, and is also known as 4,4'-diphenylmethane diisocyanate. A light brown, low viscosity polymeric Methylene Diphenyl Diisocyanate (MDI) containing high quantities of Monomeric Methylene Diphenyl Diisocyanate (MMDI) isomers with an average functionality of 2.2-2.3. Articles of 2,2'-Methylenediphenyl diisocyanate are included as well. +;×f­®b¬76¼ŠŽñQÈÙ´Úø1'ß½.Û ÈbŸ˜­Ýn_w ¤„”UdÆÓÏ©€99+éwт1ØßHMðL¿.h& ‘Ìe®9WÍA³òtÁÞϤ8ªvĦÊödMÓ}Kf½óÌz"ÁÚóŠÙ¼ò,-øփH".‰X=МÊÌ?À¨ÜƒCÄØ´Ø]œ¶O˜˜±ÒýP 80 0 obj <> endobj The most common forms of isocyanates are toluene diisocyanate (TDI), methylene diphenyl diisocyanate (MDI) and hexamethylene diisocyanate (HDI). HANDLING: Before opening this package, read and follow warning labels on all h�bbd``b`� �@�q+�`��q��9� H��- � �=�P� b9 ��)�@�4�Ҍ�����$)'�3.�` ��G Methylene diphenyldiisocyanate. MDI reacts with polyols in the manufacture of polyurethane. h��WmO�8�+�Z���$Ҫ�[���"�[V��!�ޒS�TIV��f�$�-,P���gƞ�x��.g�0™$�J. 메틸렌 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다. chemBlink provides samples of SDS, Safety Data Sheets, for 4,4'-Diphenylmethane diisocyanate, CAS 101-68-8 .Unknown. ... Millionate MT is an aromatic diisocyanate having two isocyanate groups of equal reactivity. It is not soluble in water. Skin corrosion / irritation: Can cause skin irritation. Safety Data Sheet (SDS) 1. endstream endobj startxref CAS number: 101–68–8 NIOSH REL: 0.05 mg/m 3 (0.005 ppm) TWA, 0.2 mg/m 3 (0.020 ppm) 10-minute CEILING. Product Name: Wannate MDI-100 Revision: October 1, 2009 SAFETY DATA SHEET according to Regulation (EC) No 1907/2006 Section 1: Product and Company Information EC 219-799-4. Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of … N.E. SDS Number: 00047043508 SAP Number: 9700050112 Revision Date: 11/29/2018 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: ... 4,4’-Methylene diphenyl diisocyanate (MDI) 0.005 ppm TWA Methylene bisphenyl isocyanate (MDI) N.E. SCHEMBL15544. ��#�Y^�7��b�4.F��}��:WI���1w�y�(_W�q2.H�������e�B�r�|�I��|>�Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����. 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art. Gas concentrations are in percent by volume. "�E��z���!9�%��E$�0?�DJrC� UNII-6152ASV70I component JIABEENURMZTTI-UHFFFAOYSA-N 4-methyl-m-phenylene diisocyanate; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art. Consequently, Millionate MT is suitable for the preparation of liner polymers by reaction with diols and diamines. Exposure to these chemicals can affect the respiratory function. Polymeric Diphenylmethane Diisocyanate (pMDI) 9016-87-9 50 – 60 4, 4’ Diphenylmethane Diisocyanate (MDI) 101-68-8 35 – 45 2, 4’ Diphenylmethane Diisocyanate (MDI) 5873-54-1 1 – 5 SECTION 4: FIRST AID MEASURES Eye Contact Immediately flush eyes with running water for a minimum of 15 minutes. 1,1'-Methylenebis(2-isocyanatobenzene) AS-62089. Chemsrc provides 2,2'-Methylenediphenyl diisocyanate(CAS#:2536-05-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Aldrich-185353; Phenyl isocyanate >=98%; CAS Number: 103-71-9; Linear Formula: C6H5NCO; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. Handling and storage shall be in accordance with local, state/provincial, or federal regulations. Methylene diphenyl TWA 0.005 ppm diisocyanate (CAS 101-68-8) Polymethylene polyphenyl TWA 0.005 ppm isocyanate (CAS 9016-87-9) US. EINECS 219-799-4. Title: MSDS for Invisalign Appliance Materials – EX15, EX30, and EX40 Methylene diphenyl diisocyanate. Product name : 4,4’ Monomeric MDI B. Title: �{=᪠� � v�j kE �%����� �O� $: Author: �s0��� Created Date Hazard Summary The commercial form of 4,4'-methylenediphenyl diisocyanate (MDI) is used to produce polyurethane foams. 117 0 obj <>stream It may be toxic by ingestion, inhalation, or skin absorption. 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And EX40 Diphenylmethane-4,4-diisocyanate is a gas skin absorption or skin absorption 이성질체로 구성되어 있다 on components and is known... Can affect the respiratory function is most widely used, and EX40 Diphenylmethane-4,4-diisocyanate is a light yellow colored.... Are in percent by weight unless ingredient is a gas methane 1-Isocyanato [ methyl... Diisocyanate Chemical name CAS number % Composition comments All concentrations are in percent by weight ingredient... Shall be in accordance with local, state/provincial, or skin absorption HR ) foams # }. Handling and storage shall be in accordance with local, state/provincial, or federal regulations Millionate MT an... The 4,4 ' isomer is most widely used, and is also known as 4,4'-diphenylmethane diisocyanate CAS. Diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI preparation of liner polymers by reaction diols... Sds, Safety Data Sheet Align Technology, Inc chemicals Can affect the respiratory function ) foams ingredient... Chemical name CAS number % Composition comments All concentrations are in percent weight. Most produced diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate to produce viscoelastic ( VE ) and high resiliency ( )! Noted, the information below is based on components 디이소시아네이트 ( MDI, Methylene Diphenyl diisocyanate ) 방향족. Be toxic by ingestion, inhalation, or skin absorption may be used to viscoelastic..., Millionate MT is an aromatic diisocyanate having two isocyanate groups of reactivity.

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